[Cu2(HF2)(H2O)8][FeF6]·2H2O

نویسندگان

  • Armel Le Bail
  • Anne-Marie Mercier
چکیده

The title compound, octaaqua-(hydrogenfluorido)dicopper(II) hexa-fluoridoferrate(III) dihydrate, was synthesized under hydro-thermal conditions. The Cu atom is coordinated by one F and five O atoms within a highly distorted octa-hedron, forming dimeric [Cu(2)(H(2)O)(8)HF(2)](3+) units by edge sharing. These units are hydrogen bonded to [FeF(6)](3-) anions and to an inter-stitial water mol-ecule. The former feature Fe(3+) on a special position (). The dimeric copper units are linked to adjacent dimers by F-H⋯F hydrogen bonds. Additional O-H⋯O and O-H⋯F hydrogen bonds help to consolidate the crystal packing.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009